Plasticising and melting temperature.

When the screw within the barrel of the injection moulding machine rotates, it draws material from the hopper via the feed throat and propels it along inside the barrel.Once inside, and specifically as the material passes through the compression zone on the screw, it melts or plasticises. This is due to the combined heating effect of the heater bands around the barrel and the shear heating caused by the rotation of the screw. The actual temperature of the molten material is referred to as the melt temperature.
Most thermoplastics can be processed over quite a wide melt temperature range, but the material supplier’s data sheet should always be consulted in order to identify the recommended temperature range for the material. If such data sheets are not available, the temperature ranges indicated in the below table, can be taken as a reasonable starting guide for the more commonly encountered materials. Note that these temperatures values are
for the actual melt temperature, which may differ considerably from the set temperatures on the machine barrel temperature controllers.

Table of melt temperatures.

Material                  Melt temperature range (􀁱C)

ABS                                              190–290
Acetal                                         180–220
Acrylic                                        200–250
HDPE                                          210–270
HIPS                                             180–280
LDPE                                            180–240
PA6                                                 230–290
PA66                                             270–300
PA11                                              220–250
PBTP                                              240–275
PC                                                    280–320
PP                                                    200–280
PS                                                     170–280
PVC (Flexible)                          170–190
PVC (Rigid)                                 160–210
SAN                                                 200–260

 

Measurement of Melt Temperature.

In order to measure the actual melt temperatures, about 150 cm3 melt is purged out of the cylinder into a suitable container and measured with a pyrometer. [Note: This is a potentially dangerous operation, and must be carried out with extreme care.] A needle, or
melt probe attached to a suitable pyrometer is then plunged into the melt and slowly moved around to search out the hottest spot. The maximum temperature indicated is taken to be the melt temperature.

Degradation of Materials During Plasticising.
With any material it is inadvisable to exceed the maximum melt temperature as specified by the material manufacturer. If this happens the polymer may undergo degradation, leading to changes in flow characteristics, reduction in mechanical strength, and discoloration. Overheating of heat-sensitive materials such as PVC or the acetals can lead to very rapid degradation and the liberation of substantial quantities of noxious fumes.

It should also be remembered that molten polymers, even at temperatures within the recommended processing range, can also decompose quite considerably if they are held at such temperatures for an excessively long time in the cylinder. The length of time a polymer can be held at a particular temperature without the risk of
undue degradation is known as its maximum residence time at that temperature, and this time should never be deliberately or accidentally exceeded. For this reason, it is always good practice to purge the cylinder empty if a machine has to be stopped for more than a few minutes.

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